What Happens When LNG Evaporates During Ocean Transport?
Liquefied Natural Gas (LNG) is transported at extremely low temperatures of around -162°C.
However, even with advanced insulation, a small portion of LNG naturally evaporates during the journey due to heat ingress.
This process is known as Boil-Off Gas (BOG).
Boil-Off Gas (BOG) Generation
- Approximately 0.10% – 0.15% of LNG cargo evaporates daily.
- This vapor is continuously generated due to unavoidable heat leakage.
- If not managed, it increases tank pressure.
Cargo Weathering (Composition Change)
- Lighter components like methane and nitrogen evaporate first.
- This changes the composition of LNG over time.
- The remaining LNG becomes denser with higher calorific value.
- This process is called “aging” or weathering.
Tank Pressure Management
As LNG evaporates, tank pressure rises. To prevent structural risks:
- Low-duty compressors remove BOG continuously.
- This maintains safe pressure levels inside cryogenic tanks.
Utilization of Boil-Off Gas as Fuel
Modern LNG carriers smartly use BOG as an onboard energy source:
- Steam Turbines: BOG is burned in boilers to produce steam for propulsion.
- Dual-Fuel Engines (DFDE): Engines run on both LNG and diesel.
- ME-GI Engines: High-pressure gas injection (~300 bar) provides maximum efficiency.
Reliquefaction Systems
- Advanced LNG carriers use reliquefaction plants.
- BOG is cooled and converted back into liquid LNG.
- This allows delivery of nearly 100% cargo.
Gas Combustion Unit (GCU)
- Excess gas is burned safely in a GCU.
- Used when engines cannot consume all BOG.
Risk of LNG Rollover
- Occurs when layering forms inside tanks.
- Heavier LNG settles at bottom, lighter stays on top.
- Sudden mixing can cause rapid vapor release.
Behavior of LNG in Case of Spill
- LNG is lighter than water and floats.
- Rapidly vaporizes forming a cold vapor cloud.
- Initially, vapor is heavier than air, then disperses.
- Does not mix with water and evaporates completely.
Hazards of LNG
Flammability
- Flammable only between 5%–15% concentration in air.
- Outside this range, it cannot ignite.
Explosivity
- Rapid Phase Transition (RPT) can occur without fire.
- Sudden expansion may create pressure waves.
Asphyxiation
- High gas concentration displaces oxygen.
Cryogenic Damage
- Extreme cold can freeze tissues and damage materials.
Environmental and Safety Impact
- LNG evaporates quickly, leaving minimal long-term pollution.
- Main risks are fire, explosion, and cold exposure.
- Economic impacts may include port disruption and repair costs.
Advanced Safety Understanding
Studies show that when LNG contacts water, it may undergo:
- Film Boiling: Vapor layer forms, slowing evaporation.
- Rapid Phase Transition: Sudden explosive vaporization.
Conclusion
Boil-off in LNG transport is not a flaw but a well-managed engineering advantage.
Through advanced systems like dual-fuel engines, reliquefaction units, and pressure control mechanisms, LNG carriers convert a natural physical process into an efficient energy solution.